Testing evaluates and compares the performance of propylene glycol (PG) and 1,3 propanediol (PDO) when used as a heat transfer fluid.
It is widely understood that different types of inhibitor packages can have an impact on the performance and longevity of heat transfer fluid. However, the type of glycol used also can have an impact on fluid performance in certain types of applications.
Recently, one company worked first with Penray and specialized fluids testing laboratory Amalgatech Laboratories to conduct testing to predict the performance of fluids used in environments found in common heating applications. The tests were designed to evaluate and compare the performance of propylene glycol (PG) and 1,3 propanediol (PDO) when used as a glycol in a low toxicity fluid and as a glycol in a heavy-duty fluid formulation.
Low Toxicity Fluid Comparison and Test Results
Sometimes referred to as food-grade fluids, low toxicity fluids are the HVAC industry standard, and this experiment compared the performance of a propylene glycol (PG)-based fluid against a 1,3 propanediol (PDO)-based fluid. Both fluids were made using a 50/50 dilution of glycol and water, and both were inhibited with a low toxicity, phosphate-based inhibitor package and started the experiment with a pH of 7.5. The objective of performing this research is to document how the fluid behaves over time, and especially how it protects against corrosion of various metals in heating systems.
The RPVOT is a severe test that greatly accelerates aging behaviors. The RPVOT test method evaluates the oxidation stability of fluids in the presence of two environments (air and oxygen) and introduces metals commonly found in heating systems. The first environment (air) is severe because it provides only 55 ml of fluid to protect a semi-submerged, rotating bundle of six metals commonly found in HVAC systems, assembled per ASTM D1384. Air is available at 90 psig pressure. The bundle is rotated at an angle in the fluid and the temperature is maintained at 239°F (115°C).
In the second environment (oxygen), the severity is increased by changing the atmosphere to pure oxygen and increasing the temperature to 302°F (150°C). The second environment is useful because it presents a worst-case scenario. The test method generally will help distinguish between fluids that are definitely unstable and deleterious from the corrosion standpoint, and those that are suitable for further evaluation as extended life (ELC) formulations.
In addition to measuring the weight loss of each metal specimen, an analysis of the exposed fluid was performed. The condition of the used fluid may be compared to the typical values of the unused fluid to assist in understanding the aging mechanisms and behaviors of the fluid formulation being tested. This test method greatly accelerates the oxidation aging of both the base fluid (i.e., glycol) and corrosion-inhibitor components. The analysis performed is appropriate to the inhibitor package; it is not necessary to analyze for components that are not used in the sample tested.
Low Toxicity Fluid Comparison Results. In the pressurized air environment 239°F (115°C), there was little difference in the performance between the PG-based, low toxicity fluid and the PDO-based, low toxicity fluids, which appeared clear and had a pH of 7.5 prior to testing. After being tested in the oxygenated, high temperature environments, both fluids became acidic, and neither fluid provided strong protection against corrosion of copper.
However, after exposure to the pressurized oxygen environment, the PG-based fluid exhibited a lower pH level and had higher levels of organic acids than the PDO-based fluid. Interestingly, the pathway for PDO breakdown is different than that of PG, which was demonstrated by the lower levels of glycolate and formate found in the PDO-based fluid. Lower levels of organic acids in the PDO-based fluid offer an explanation as to why — though the fluid did not fully protect against corrosion — the PDO-based fluid demonstrated lower levels of copper and zinc after oxidization.
Heavy-Duty Fluid Comparison
Heavy-duty fluids are used in applications such as industrial generators, oil-and-gas processing equipment and solar thermal equipment for producing hot water and heat. This experiment compared the performance of propylene-glycol-based heavy-duty fluids against 1,3 propanediol-based heavy-duty fluids.
For the first test method, both fluids were made using a 50/50 dilution of glycol and deionized water, and both were inhibited with a heavy-duty OAT inhibitor package. Per ASTM D1384, metals typically present in cooling systems are totally immersed in aerated fluids for 336 hours at 190°F (88°C). The objective of performing this research is to document how heavy-duty heat transfer fluid behaves over time at high temperatures. Doing so assists in determining whether or not the fluids are suitable for heavy-duty heat transfer fluid applications.
For the second test method, both fluids were made using a 50/50 dilution of glycol and deionized water, and both were inhibited with a low-silicate, phosphate-free inhibitor package made by Penray (No. 2792).
The fluids were boiled in a reflux system for 16 hours at 377°F ±18°F (192°C ±10°C). This period of reflux was intended to simulate a stagnant high thermal event for a semi-closed-loop heat transfer system.
Heavy-Duty Fluid Comparison Results. There was not a significant difference in fluid performance between PG-based fluids and PDO-based fluids with heavy-duty OAT inhibitors at 190°F (88°C) for 336 hours. The OAT inhibitor package successfully prevented corrosion of metal specimens, including copper, regardless of whether the glycol used in the fluid was PDO-based or PG-based.
There was a significant difference in the performance of the two fluids in the 377°F (192°C) reflux system for 16 hours. The PDO-containing heat transfer fluid was shown to have improved stability to thermal decomposition when compared to the PG-containing heat transfer fluid, exhibited by lower levels of in the PDO-based fluid after testing.
In conclusion, these results suggest that for heating applications that do not demand a high-performance heat transfer fluid, the type of glycol used in the fluid formulation is likely not the primary point of consideration when choosing a product. For applications in which a heat transfer fluid is exposed to high temperatures, however, the type of glycol used in the formulation may have a significant impact on the performance of the fluid and may be taken into consideration when filling a system. The performance of the glycol was shown to have the most significant impact in both the low toxicity fluid at 302°F (150°C) and in the heavy-duty fluid in the solar-thermal simulated environment at 377°F (192°C). After being exposed to both of those testing environments, the PDO-based fluids exhibited lower levels of organic acids and demonstrated better thermal stability than the PG-based fluids.